Wood Polymer Composites Based on the Recycled Polyethylene Blends from Municipal Waste and Ethiopian Indigenous Bamboo (Oxytenanthera abyssinica) Fibrous Particles Through Chemical Coupling Crosslinking

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Abstract

Valorization of potential thermoplastic waste is an effective strategy to address resource scarcity and reduce valuable thermoplastic waste. In this study, new ecofriendly biomass-derived wood polymer composites (WPCs) were produced from three different types of recycled polyethylene (PE) municipal waste, namely linear low-density polyethylene (LLDPE), medium-density polyethylene (MDPE), or high-density polyethylene (HDPE), and their blend with equal composition (33/33/33 by wt.%). Bamboo particle reinforcement derived from indigenous Ethiopian lowland bamboo (LLB), which had never been utilized before in a WPC formulation, was used as the dispersed phase. Before utilization, recycled LLDPE, MDPE, and HDPE were carefully characterized to determine their chemical compositions, residual metals, polycyclic aromatic hydrocarbons, and thermal properties. Similarly, the fundamental mechanical properties of the WPCs, such as tensile strength, modulus of elasticity, flexural strength, modulus of rupture, and unnotched impact strength, were evaluated. Finally, the thermal stability and interphase coupling efficiency of maleic-anhydride-grafted polypropylene (MAPP) were carefully investigated. WPCs formulated by melt-blending either of the recycled PEs or the blend of recycled PE with bamboo particles showed significant improvement due to MAPP enhancing interfacial adhesion and thermally induced crosslinking, despite inherent immiscibility. These results were confirmed using Fourier transform infrared spectroscopy, scanning electron microscopy, and thermogravimetric analysis. The formulated WPCs may promote PE waste cascading valorization, offering sustainable alternatives and maximizing LLB utilization. Furthermore, comparison with well-known standards for polyolefin-based WPCs indicated that the prepared WPCs can be used as alternative sustainable building materials and related applications.

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